Raman Spectra from Laser-Processed Lead Zirconate Titanate (PbZr0.3Ti0.7O3) Prepared by a Sol-Gel Process

Author:

Gernet D.1,Kiefer W.1,Schmidt H.1

Affiliation:

1. Institut für Physikalische Chemie, Universität Würzburg, Marcusstraβe 9-11, D-8700 Würzburg, Germany (D.G., W.K.); and Institut für Neue Materialien, Gebäude 43, Universität des Saarlandes, 1m Stadtwald, D-6600 Saarbrücken, Germany (H.S.)

Abstract

We report on investigations of laser-induced crystallization of PbZr0.3Ti0.7O3 (PZT) gel-powder. By means of micro-Raman spectroscopy, and of optical and scanning electron micrography (SEM), we show that, upon laser irradiation, amorphous PZT material is transformed into microcrystals of the perovskite structure. It was found that the laser-induced crystallization is much faster than crystallization through calcination in a conventional oven.

Publisher

SAGE Publications

Subject

Spectroscopy,Instrumentation

Reference11 articles.

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3. Raman Spectra of Polycrystalline Solids; Application to thePbTi1−xZrxO3System

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1. MICRO-RAMAN SPECTROSCOPY CHARACTERIZATION OF DELLA ROBBIA GLAZES;Archaeometry;2007-11

2. Wolfgang Kiefer;Journal of Raman Spectroscopy;2006-01

3. Infrared and Raman Spectroscopy;Ullmann's Encyclopedia of Industrial Chemistry;2000-09-15

4. A differential anomalous X-ray scattering study of the formation of lead zirconate titanate via sol-gel process;Berichte der Bunsengesellschaft für physikalische Chemie;1997-06

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