Stopped-Flow Rapid-Scan Fourier Transform Infrared Spectroscopy-Reference-Cited by-同舟云学术

Stopped-Flow Rapid-Scan Fourier Transform Infrared Spectroscopy

Published:1999-03 Issue:3 Volume:53 Page:292-296
ISSN:0003-7028
Container-title:Applied Spectroscopy
language:en
Short-container-title:Appl Spectrosc

Author:

Dunn Brian C.¹,Eyring Edward M.¹

Affiliation:

1. Department of Chemistry, University of Utah, Salt Lake City, Utah 84112

Abstract

A stopped-flow rapid-mixing device interfaced with a rapid-scan FT-IR spectrometer and a diode-array UV-visible spectrophotometer permits the observation of reaction transient intermediates over a broad range of wavelengths at minimal cost. The system has been evaluated for both spectral regions with the use of two different chemical reaction systems. The presence of a transient intermediate is clearly indicated in one case. Unexpected reactivity was observed in the other case. This approach will allow the study of chemical reactions even when no spectral changes occur in the UV-visible region.

Publisher

SAGE Publications

Subject

Spectroscopy,Instrumentation

Link

http://journals.sagepub.com/doi/pdf/10.1366/0003702991946677

Reference12 articles.

1. Molecular Reaction Mechanisms of Proteins Monitored by Nanosecond Step-Scan FT-IR Difference Spectroscopy

2. Photochemical Release of ATP from "Caged ATP" Studied by Time-Resolved Infrared Spectroscopy

3. Ten-Nanosecond Step-Scan FT-IR Absorption Difference Time-Resolved Spectroscopy: Applications to Excited States of Transition Metal Complexes

4. Step-Scan FT-IR Spectroelectrochemical Analysis of Surface and Solution Species in the Ferricyanide/Ferrocyanide Redox Couple

5. Study of Impulse Polymer Rheo-Optics by Step-Scan FT-IR Time-Resolved Spectroscopy

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