Infrared-Emitting Species Identified in the Combustion of Boron-Based Pyrotechnic Compositions-Reference-Cited by-同舟云学术

Infrared-Emitting Species Identified in the Combustion of Boron-Based Pyrotechnic Compositions

Published:1997-09 Issue:9 Volume:51 Page:1400-1404
ISSN:0003-7028
Container-title:Applied Spectroscopy
language:en
Short-container-title:Appl Spectrosc

Author:

Smit Kenneth J.¹,Hancox Ronald J.¹,Hatt David J.¹,Murphy Shane P.¹,De Yong Leo V.¹

Affiliation:

1. AMRL, DSTO-Melbourne, P.O. Box 4331, Melbourne VIC 3001, Australia

Abstract

Measurement of infrared emission spectra for boron-based pyrotechnic combustion has enabled the elucidation of a number of boron oxidation products. The raw spectra were corrected for instrument responsivity and atmospheric attenuation for the region 1500 to 3000 cm−1. The alkali metal metaborates and boron oxide (B2O3) were among the principal combustion products depending on which of three different oxidants were used. In addition, thermochemical modeling studies were undertaken on each composition to predict the combustion products. The thermochemical modeling data were qualitatively in agreement with the identified combustion products.

Publisher

SAGE Publications

Subject

Spectroscopy,Instrumentation

Link

http://journals.sagepub.com/doi/pdf/10.1366/0003702971942114

Reference27 articles.

1. Observation of infrared emission spectra from silicon combustion products

2. Ignition and combustion of small boron lumps in an oxygen stream

3. Boron slurry-fueled jet engine exhaust plume infrared signatures

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