The Application of NIR Spectroscopy for the Prediction of Properties of Australian Refined Reformate

Author:

Asker N.1,Kokot S.1

Affiliation:

1. Department of Chemistry, Queensland University of Technology, GPO Box 2434, Brisbane 4000, Australia

Abstract

A rapid NIR method for the determination of octane number of reformate samples of Australian refined motor gasoline is described. Results of predictions using calibration sets based on ASTM full blends and actual reformate samples are presented. Interpretation of spectral data using principal component analysis facilitates the selection of a suitable analytical spectral range and demonstrates that the reformate samples may be distinguished on the basis of the geographical origins of the parent crude oils. The described method forms a basis for practical application and is a possible alternative to the standard CFR engine test method.

Publisher

SAGE Publications

Subject

Spectroscopy,Instrumentation

Reference16 articles.

1. Manual on Significance of Tests for Petroleum Products, Duroff V. G. Ed. (ASTM, Philadelphia, 1989), 5th ed., Chap. 4, p. 31.

2. Gary J. H. and Handwerk G. E, Petroleum Refining Technology and Economics (Marcel Dekker, New York, 1984), 2nd ed., p. 8.

3. Annual Book of ASTM Standards, Petroleum Products, Lubricants and Fossil Fuels (ASTM, Philadelphia, 1990), Vol. 05.04, pp. 13, 21, 26.

4. Materials Characterization Using Factor Analysis of FT-IR Spectra. Part 2: Mathematical and Statistical Considerations

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