Solution Infrared and Nuclear Magnetic Resonance Studies of Cellulose Nitrates-Reference-Cited by-同舟云学术

Solution Infrared and Nuclear Magnetic Resonance Studies of Cellulose Nitrates

Published:1991-05 Issue:4 Volume:45 Page:604-610
ISSN:0003-7028
Container-title:Applied Spectroscopy
language:en
Short-container-title:Appl Spectrosc

Author:

Saunders C. William¹,Taylor Larry T.¹

Affiliation:

1. Department of Chemistry, Virginia Polytechnic Institute and State University, Blacksburg, Virginia 24061-0212

Abstract

This study has identified the infrared asymmetric nitrate absorptions of cellulose nitrates observed in THF solution. Independent absorptions for the primary nitrate at C6 and secondary nitrate at C3 were observed at 1651 cm−1 and 1639 cm−1, respectively. In addition, a third absorption at 1667 cm−1 was observed to be dependent upon the degree of nitration of the cellulose nitrate. This absorption was found to be due to steric hindrance between secondary nitrate groups on the C2 and C3 sites.

Publisher

SAGE Publications

Subject

Spectroscopy,Instrumentation

Link

http://journals.sagepub.com/doi/pdf/10.1366/0003702914337001

Reference17 articles.

1. Reveley A., in Cellulose and Its Derivatives, Kennedy J. F., Phillips G. O., Wedlock D. J., Williams P. A., Eds. (Ellis Horwood, Chichester, 19?), pp. x–x.

2. “Cellulose Derivatives, Esters,” Kirk-Othmer Encylopedia of Chemical Technology (Publisher, Location, 1979) 3rd ed., Vol. 5.

3. Infrared Determination of Nitrocellulose in Mixtures of Cellulose Resins

4. Determination of Nitrogen in Nitrocellulose by Infrared Spectrometry.

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