Spatially Resolved Vibrational Temperature Profiles in Flames from Molecular Absorption Spectroscopy

Author:

Huie Carmen W.1,Yeung Edward S.1

Affiliation:

1. Ames Laboratory and Department of Chemistry, Iowa State University, Ames, Iowa 50011

Abstract

A highly collimated laser beam is used to observe molecular absorption in a premixed air-acetylene flame by providing a two-dimensional image on a vidicon camera Spatially resolved molecular concentrations can thus be obtained in 1/60 second By measurement of the relative intensities of absorption from different vibrational levels in the ground state of the molecules, a vibrational temperature can be derived for each of the spatial regions in the flame This information is directly relevant to the understanding of dissociation in flames

Publisher

SAGE Publications

Subject

Spectroscopy,Instrumentation

Reference13 articles.

1. Die Temperatur der Acetylen-Sauerstoffflamme

2. Lewis B. and von Elbe G., Combustion, Flames and Explosions of Gases (Academic Press, New York, 1951), p. 261.

3. Laser diagnostics of flames, combustion products, and sprays

4. Spatial mapping of concentrations in pulsed and continuous atom sources

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