Surface Studies of the Nickel Electrode System Using a Special Transfer Cell-Reference-Cited by-同舟云学术

Surface Studies of the Nickel Electrode System Using a Special Transfer Cell

Published:1988-05 Issue:4 Volume:42 Page:658-666
ISSN:0003-7028
Container-title:Applied Spectroscopy
language:en
Short-container-title:Appl Spectrosc

Author:

Sherwood Peter M. A.¹,Welsh Ian D.¹,Hercules David M.¹

Affiliation:

1. Department of Inorganic Chemistry, The University, Newcastle upon Tyne, NE1 7RU, U.K. (P.M.A.S.); and Department of Chemistry, University of Pittsburgh, Pittsburgh, Pennsylvania 15260, U.S.A. (I.D.W., D.M.H.)

Abstract

Nickel metal with an unoxidized and an electrochemically oxidized surface can be transferred considerable distances between vacuum systems, without significant surface change, in an anaerobic cell for study by various surface science methods (XPS, Auger, ISS, and SIMS). The SIMS and ISS spectra are very sensitive to hydrocarbon contamination, which can be nearly eliminated by using the transfer cell. Complementary information is obtained using these surface analytical methods. Electrochemically oxidized nickel metal samples show the presence of oxide and hydroxide species. The results are compared with spectral data for a number of nickel compounds.

Publisher

SAGE Publications

Subject

Spectroscopy,Instrumentation

Link

http://journals.sagepub.com/doi/pdf/10.1366/0003702884429337

Reference28 articles.

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