Wide Range Two-Crystal Vacuum X-ray Spectrometer for Chemical State Analysis-Reference-Cited by-同舟云学术

Wide Range Two-Crystal Vacuum X-ray Spectrometer for Chemical State Analysis

Published:1982-03 Issue:2 Volume:36 Page:171-174
ISSN:0003-7028
Container-title:Applied Spectroscopy
language:en
Short-container-title:Appl Spectrosc

Author:

Gohshi Y.¹,Kamada H.¹,Kohra K.¹,Utaka T.¹,Arai T.¹

Affiliation:

1. Department of Industrial Chemistry, University of Tokyo, 7-3-1 Hongo, Bunkyo, Tokyo, 113 Japan (Y.G., H.K., K.K.), and Rigaku Industrial Corp., 14-8 Akaoji, Takatsuki, 569 Japan (T.U., T.A.)

Abstract

The design and construction of a new two-crystal x-ray spectrometer are described together with the observed Mg Kα, Al Kα, Si Kα, S Kα, and Cu Kα1 spectra. The spectrometer is designed for x-ray fluorescence analysis and has a wide scanning range (2° to 146° 2θ) under vacuum. Excellent reproducibility of 0.4 s in arc is attainable, which makes possible the observation of chemical shifts in x-ray spectra. Magnesium Kα was found to be influenced by the coordination number, proving that the spectrometer is useful for chemical state analysis.

Publisher

SAGE Publications

Subject

Spectroscopy,Instrumentation

Link

http://journals.sagepub.com/doi/pdf/10.1366/0003702824638908

Reference11 articles.

1. Measurement of the Mo.K Doublet Distances by Means of the Double X-Ray Spectrometer

2. Über die natürliche Breite der Röntgenemissionslinien. I.

3. Über die natürliche Breite der Röntgenemissionslinien. II.

4. For review, Compton A. H. and Allison S. K., X-Rays in Theory and Experiment (D. van Nostrand, New York, 1935); Thomsen J. S., in X-ray Spectroscopy, Azaroff L. V., Ed. (McGraw-Hill, New York, 1974); Agarwal B. K., X-ray Spectroscopy (Springer-Verlag, New York, 1979), p. 346.

5. Two‐Crystal, Vacuum Monochromator

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