Raman Spectroscopic Evidence of Pressure-Induced Conformational Changes in Liquid Methylcyclohexane-Reference-Cited by-同舟云学术

Raman Spectroscopic Evidence of Pressure-Induced Conformational Changes in Liquid Methylcyclohexane

Published:1984-05 Issue:3 Volume:38 Page:313-317
ISSN:0003-7028
Container-title:Applied Spectroscopy
language:en
Short-container-title:Appl Spectrosc

Author:

Gardiner Derek J.¹,Bassi Gurmail S.¹,Galvin Gerry D.¹,Gorvin Anthony C.¹,Straughan Brian P.¹

Affiliation:

1. School of Chemical and Life Sciences, Newcastle upon Tyne Polytechnic, Newcastle upon Tyne, England NE1 8ST (D.J.G., G.S.B., G.D.G., A.C.G.); and Department of Inorganic Chemistry, University of Newcastle upon Tyne, Newcastle upon Tyne, England NE1 7RU (B.P.S.)

Abstract

Raman spectra have been obtained from liquid methylcyclohexane over a range of temperatures (–64°C + 64°C) and pressures (1 bar to 5 kbar). Comparison of the pattern of band intensity changes as a function of temperature and pressure indicates that an increase in pressure shifts the conformational equilibrium in the liquid to favor the equatorial form.

Publisher

SAGE Publications

Subject

Spectroscopy,Instrumentation

Link

http://journals.sagepub.com/doi/pdf/10.1366/0003702844555638

Reference13 articles.

1. Pressure induced changes in liquid alkane chain conformation

2. Effect of pressure on molecular conformations. II. Trans–gauche equilibrium of 1,2‐dichloroethane and 1,2‐dibromoethane

3. Effect of pressure on molecular conformations. III. Internal rotation angle in gauche‐1,2‐dichloroethane and gauche‐1,2‐dibromoethane

4. Pressure effects on conformational equilibrium in solution. Infrared studies of halocyclohexanes

Cited by 13 articles. 订阅此论文施引文献订阅此论文施引文献，注册后可以免费订阅5篇论文的施引文献，订阅后可以查看论文全部施引文献

1. Pressure and Composition Effects on a Common Nanoparticle Ligand–Solvent Pair;The Journal of Physical Chemistry B;2024-01-10

2. Raman and infrared spectra, quantum chemical calculations, conformations and spectral assignments of 1-chloro-1-methyl-1-silacyclohexane;Journal of Molecular Structure;2013-09

3. Infrared and Raman spectra, conformations, quantum chemical calculations and spectral assignments of 1-methyl-1-silacyclohexane;Journal of Molecular Structure;2013-02

4. Liquid organization and solvation properties at polar solid/liquid interfaces;Faraday Discussions;2013

5. The fluorine effect: photophysical properties of borondipyrromethene (bodipy) dyes appended at the meso position with fluorinated aryl groups;RSC Advances;2012