The KBM Equation for Solvent-Induced Frequency Shifts Revisited-Reference-Cited by-同舟云学术

The KBM Equation for Solvent-Induced Frequency Shifts Revisited

Published:1989-09 Issue:7 Volume:43 Page:1208-1211
ISSN:0003-7028
Container-title:Applied Spectroscopy
language:en
Short-container-title:Appl Spectrosc

Author:

Nyquist R. A.¹

Affiliation:

1. The Dow Chemical Company, Analytical Sciences Laboratory, 1897 Building, Midland, Michigan 48667

Abstract

The KBM equation for determining solvent frequency shifts is generally useless for predicting vC = O frequencies for compounds in various solvent systems. The vC = O frequencies for acetone and tetramethylurea in various solvents do not correlate with dielectric effects (ε) of the solvent. A series of factors most likely determine the extent of solute/solvent-induced vibrational mode frequency shifts.

Publisher

SAGE Publications

Subject

Spectroscopy,Instrumentation

Link

http://journals.sagepub.com/doi/pdf/10.1366/0003702894203435

Reference7 articles.

1. Hallam H. E., Infra-Red Spectroscopy and Molecular Structure, Davies M., Ed. (Elsevier, New York, 1963), p. 420.

2. On the Theory of Optical Rotatory Power

3. Sur la déformation des molécules en phase condensée et la « liaison hydrogène »

4. A New Analysis of the Effect of Polar Solvents Uponv(NH) of Pyrrole

5. Infra-red spectra and solvent effects. Part 5.—Solvent effects on XO dipoles and on rotational isomers

Cited by 39 articles. 订阅此论文施引文献订阅此论文施引文献，注册后可以免费订阅5篇论文的施引文献，订阅后可以查看论文全部施引文献

1. DFT-Based Linear Solvation Energy Relationships for the Infrared Spectral Shifts of Acetone in Polar and Nonpolar Organic Solvents;The Journal of Physical Chemistry A;2008-02-20

2. Band-Target Entropy Minimization (BTEM): An Advanced Method for Recovering Unknown Pure Component Spectra. Application to the FTIR Spectra of Unstable Organometallic Mixtures;Organometallics;2002-04-22

3. Re-Examination of the Effect of Aprotic Solvents upon the Fundamental Vibrational Peak of the Carbonyl Group in 1,1,3,3-Tetramethylurea;Applied Spectroscopy;1999-01

4. On the number of observable species, observable reactions and observable fluxes in chemometric studies and the role of multichannel integration;Analytica Chimica Acta;1997-09

5. A Generalized Solvent Acidity Scale: The Solvatochromism ofo-tert-Butylstilbazolium Betaine Dye and Its Homomorpho,o′-Di-tert-butylstilbazolium Betaine Dye;Liebigs Annalen;1997-09