Infrared Characterization of Uranium Oxide Powders Using a Metal Light Pipe

Author:

Cort B.1,Andrew J. F.1,Hansen G. J.1

Affiliation:

1. Materials Science and Technology Division, Los Alamos National Laboratory, Los Alamos, New Mexico 87545

Abstract

A light-pipe technique has been used to measure infrared spectra of U02, U3O8, and UO3, in the range 2000 to 450 cm−1. Comparison with transmission spectra found in the literature indicates that the technique is very suitable for characterization of actinide powders and will therefore be a useful tool for future work, especially with hazardous materials such as actinides. The spectra obtained show all features predicted by group theory calculations, and the spectrum for the trioxide exhibits previously unseen features characteristic of uranyl bonds.

Publisher

SAGE Publications

Subject

Spectroscopy,Instrumentation

Reference7 articles.

1. The uranium-oxygen system: U3O8-UO3

2. Infrared spectroscopy of the uranium/oxygen system

3. Raman spectra of oxides with the fluorite structure

4. Hair M. L., Infrared Spectroscopy in Surface Chemistry (Marcel Dekker, Inc., New York, 1967), p. 59.

5. Bohren C. F. and Huffman D. R., Absorption and Scattering of Light by Small Particles (John Wiley and Sons, New York, 1983), pp. 228–232.

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