Production of DF* from Polytetrafluoroethylene and Deuterium Plasma as Observed in the Mid-Infrared by Fourier Transform Infrared Spectroscopy-Reference-Cited by-同舟云学术

Production of DF* from Polytetrafluoroethylene and Deuterium Plasma as Observed in the Mid-Infrared by Fourier Transform Infrared Spectroscopy

Published:1980-07 Issue:4 Volume:34 Page:408-410
ISSN:0003-7028
Container-title:Applied Spectroscopy
language:en
Short-container-title:Appl Spectrosc

Author:

Gallaher T. N.¹,DeVore T. C.¹,Carter R. O.¹,Anderson C.¹

Affiliation:

1. Department of Chemistry, James Madison University, Harrisonburg, Virginia 22807 (T.N.G., T.C.D.), Department of Chemical Sciences, Old Dominion University, Norfolk, Virginia 23508 (R.O.C.), and Nicolet Instrument Corp., 5225 Verona Road, Madison, Wisconsin 53711 (C.A.)

Abstract

The reaction of a deuterium plasma and polytetrafluoroethylene has been investigated. Vibrationally excited DF* (up to v′ = 3) has been observed in emission via Fourier transform infrared spectroscopy. The vibrational and rotational temperatures suggest that a mechanism similar to that found previously for the reaction between H atoms and the fluoroethylenes is responsible for the production of the DF.

Publisher

SAGE Publications

Subject

Spectroscopy,Instrumentation

Link

http://journals.sagepub.com/doi/pdf/10.1366/0003702804731429

Reference6 articles.

1. Characteristics of a multidipole ion source

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3. The Infra-Red Spectrum and Molecular Constants of HF and DF

4. Infrared chemiluminescence from the reaction of hydrogen atoms with fluoroethylenes

5. Overtone emission spectroscopy of HF and DF: Vibrational matrix elements and dipole moment function

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