Capillary Discharge Lamp for the Direct Determination of Iodine by Flame Atomic Absorption Spectroscopy

Author:

Lowe M. D.1,Sutton M. M.1,Clinton O. E.1

Affiliation:

1. Spectrochemical Laboratory, Ruakura Soil and Plant Research Station, Private Bag, Hamilton, New Zealand

Abstract

A simple and inexpensive iodine capillary discharge lamp has been developed. The spectrum of iodine was produced by maintaining a current-limited alternating current discharge in a helium-iodine vapor mixture flowing through a quartz capillary discharge tube. The performance of this spectral lamp as a source of resonance radiation for atomic absorption spectroscopy was evaluated using both unshielded and argon-shielded air-acetylene and nitrous oxide-acetylene flames. Sensitivities and detection limits for iodine obtained using the reported spectral source were found to compare favorably with data reported by other workers who used an electrodeless discharge lamp and a modified hollow cathode lamp.

Publisher

SAGE Publications

Subject

Spectroscopy,Instrumentation

Reference23 articles.

1. Christian G. D. and Feldman F. J., Atomic Absorption Spectroscopy: Applications in Agriculture, Biology and Medicine (Wiley-Interscience, New York, 1970). pp. 182–183.

2. Mavrodineanu R., Ed. Analytical Flame Spectroscopy, Selected Topics (Macmillan, London, 1970), pp. 353–356.

3. Molecular-emission spectroscopy in cool flames. Part IV. The determination of chloride, bromide and iodide by thermal-emission spectroscopy in the presence of indium salts

4. In-flame gas-solid interactions for simultaneous determination of iodide and bromide on the parts-per-billion level

5. Determination of iodide and bromide by molecular absorption spectrophotometry following oxidation

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