Site-Selection Phosphorimetry via Singlet-State Excitation-Reference-Cited by-同舟云学术

Site-Selection Phosphorimetry via Singlet-State Excitation

Published:1988-01 Issue:1 Volume:42 Page:65-68
ISSN:0003-7028
Container-title:Applied Spectroscopy
language:en
Short-container-title:Appl Spectrosc

Author:

Vo-Dinh Tuan¹,Lamotte Michael¹

Affiliation:

1. Advanced Monitoring Development Group, Health & Safety Research Division, Oak Ridge National Laboratory, Oak Ridge, Tennessee 37831-6101, U.S.A. (T. V.-D.); and Laboratorie de Chimie Physique A, University of Bordeaux, 33405 Talence, France (M.L.)

Abstract

This paper describes the technique of excitation energy site-selection (SS) phosphorimetry for chemical analysis of polycyclic aromatic compounds in Shpolskii matrices at 4.2 K. The principle of the SS phosphorescence technique, which uses excitation via the singlet state and produces narrow-band phosphorescence, is discussed. The analysis of a three-component mixture is used to illustrate the spectral selectivity of the SS phosphorimetric technique.

Publisher

SAGE Publications

Subject

Spectroscopy,Instrumentation

Link

http://journals.sagepub.com/doi/pdf/10.1366/0003702884428536

Reference27 articles.

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4. The detection and determination of polynuclear aromatic hydrocarbons by luminescence spectrometry utilising the Shpol'skii effect at 77 K

5. Dispersion states and orientation of aromatic solutes in monocrystalline matrices ofn‐heptane

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1. Water monitoring of polycyclic aromatic hydrocarbons by laser-excited time-resolved Shpol'skii spectrometry with fiber optic probes;SPIE Proceedings;2002-02-22

2. Fiber-Optic System for 77 K Phosphorescence Lifetime Measurements of Polycylic Aromatic Compounds in Shpol'skii Matrices;Applied Spectroscopy;2001-09

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4. Shpolskii Spectra of trans-1,2-Di(2'-pyridyl)ethylene. Identification and Evidence for Almost Planar Structure and .pi. Type HMO for the Trapped Rotamer;The Journal of Physical Chemistry;1994-11

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