Analysis of the Effluent from a High Voltage Spark Discharge with a Microwave-Induced Plasma

Author:

Helmer Deborah J. C.1,Walters J. P.1

Affiliation:

1. Department of Chemistry, University of Wisconsin, Madison, Wisconsin 53706

Abstract

A high voltage spark discharge was used to sample ferrous alloy samples in a point-to-plane configuration. An enclosed Petry spark stand was used so that the effluent from the spark could be put into a microwave discharge sustained at 2450 MHz. The emission from the eroded metals in the microwave discharge was monitored with a PARC Vidicon detector. This method of detection provided spectral simplification and improved signal-to-background ratios up to six-fold over the emission observed from the spark discharge. The emission from the microwave was shown to be linear with concentration for many lines observed.

Publisher

SAGE Publications

Subject

Spectroscopy,Instrumentation

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1. Microwave Plasma Systems in Optical and Mass Spectroscopy;Encyclopedia of Analytical Chemistry;2016-09-16

2. Measurement of elemental concentration of aerosols using spark emission spectroscopy;Journal of Analytical Atomic Spectrometry;2012

3. Microwave Plasma Systems in Optical and Mass Spectroscopy;Encyclopedia of Analytical Chemistry;2011-12-15

4. Microwave-Induced Plasma Systems in Atomic Spectroscopy;Encyclopedia of Analytical Chemistry;2000-10-30

5. Direct solid atomic emission spectrometric analysis of metal samples by an argon microwave plasma torch coupled to spark ablation;Spectrochimica Acta Part B: Atomic Spectroscopy;1999-09

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