Experimental evaluation of biolubricant with additive nanoparticle calcium carbonate (CaCO₃) from scallop shell waste as cutting fluids using minimum quantity lubrication (MQL) in CNC milling process

Abstract

Nano-cutting fluid sprayed using the minimum quantity lubricant (MQL) method is one example of a green manufacturing process. Meanwhile, vegetable oil is an appropriate lubricating base oil as it offers very high lubricating performance and environmental friendliness. Further, CaCO₃ nanoparticles are popular for their capacity to improve lubrication properties and performance. However, the optimum impact of utilizing different types of vegetable oil remains inadequately investigated. Therefore, this study aims to analyze the effect of CaCO₃ nanoparticles on the performance of cutting fluid, specifically on the thermophysical, rheological, and tribological properties in the CNC milling process of AISI 1045 Steel material. The nano-cutting fluid was prepared using different vegetable oils (canola, corn, soybean) added with CaCO₃ nanoparticles with a mass concentration of 0.15%. The results showed that the thermophysical properties, including density and viscosity, were highest when using canola oil, and the addition of CaCO₃ to all samples did not significantly affect thermal conductivity. Meanwhile, for the rheological properties, we observed Newtonian for all cutting fluid samples. For tribological properties, canola, and corn oil were better for obtaining a minimum Ra value, while soyabean oil was more effective in reducing cutting temperature. Based on the results of tool wear calculations, each oil presents the best performance in reducing wear, especially with the addition of CaCO₃. For chip formation, on average, the samples produce irregular tooth morphology with C-type, comma, and elongation shapes. Meanwhile, the resulting chip color was dark purple, which changed to dark brown and light brown, then turned silvery white due to wear and tear on the different sides of the chisel.