Potentiometric Determination of the Ion-Pair Formation Constant of a Univalent Cation-Neutral Ligand Complex with an Anion in Water Using an Ion-Selective Electrode.-Reference-Cited by-同舟云学术

Potentiometric Determination of the Ion-Pair Formation Constant of a Univalent Cation-Neutral Ligand Complex with an Anion in Water Using an Ion-Selective Electrode.

Published:1999 Issue:6 Volume:15 Page:597-599
ISSN:0910-6340
Container-title:Analytical Sciences
language:en
Short-container-title:Anal. Sci.

Author:

KUDO Yoshihiro¹,KATSUTA Shoichi¹,TAKEDA Yasuyuki¹

Affiliation:

1. Department of Chemistry, Faculty of Science, Chiba University

Publisher

Springer Science and Business Media LLC

Subject

Analytical Chemistry

Link

http://www.jstage.jst.go.jp/article/analsci/15/6/15_6_597/_pdf

Reference7 articles.

1. 1. Y. Takeda, A. Kawarabayashi, K. Takahashi and Y. Kudo, Bull. Chem. Soc. Jpn., 68, 1309 (1995).

2. 2. Y. Takeda, A. Kawarabayashi, K. Endo, T. Yahata, Y. Kudo and S. Katsuta, Anal. Sci., 14, 215 (1998).

3. 3. Since K_MX=([MX]_t-[M⁺])/[M⁺]² in a solution of MX, the K_MX value can also be determined by potentiometry with a M⁺-ISE.

4. 4. It is assumed that (i) Na⁺-ISE employed responds to only uncomplexed sodium ion and (ii) the liquid junction poten-tial between the solution of (C₂H₅)₄NCl or (C₂H₅)₄NClO₄ and the test solution is constant within experimental errors.

5. 5. The log K_Na(18C6)Pic value was calculated by using the K_Na(18C6) value of 10^0.73 mol^-1 dm³ at I=(1 - 5)×10^-3 mol dm^-3. See, Y. Takeda, Y. Mochizuki, M. Tanaka, Y. Kudo, S. Katsuta and M. Ouchi, J. Incl. Phenom., 33, 217 (1999).

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