Spectrophotometric Determination of the Partition Constant for Five .BETA.-Diketones in Triton X-100 Micellar Systems.

Author:

INABA Kazuho1

Affiliation:

1. The National Institute for Environmental Studies

Publisher

Springer Science and Business Media LLC

Subject

Analytical Chemistry

Reference16 articles.

1. Unusually Slow Extraction Rate and Mechanism of Iron(III) with Trifluoroacetylacetone in Triton X-100 Micellar System. Part I. Extraction Routes.

2. Unusually Slow Extraction Rate and Mechanism of Iron(III) with Trifluoroacetylacetone in Triton X-100 Micellar System. Part II. Interfacial Transport.

3. 3. K. Inaba, “Value Adding Through Solvent Extraction”, ed. D. C. Shallcross, R. Paimin, and L. M. Prvcic, 1996, Vol. 1, University of Melbourne, Melbourne, 57.

4. Extractability and Solubilization Locus of Six β-Diketones and Their Iron(III) Complexes in Triton X-100 Micellar Solutions

5. 5. The calculation was made by considering the entire complex species in the bulk aqueous phase (i.e., FeA2+, FeA2+ and FeA3) for AA and TFA systems, and by the mono-complex species in the bulk aqueous phase for BZA system, while no complex species was considered to exist in the bulk aqueous phase during the calculations for BFA and TTA systems. All the absorbance for the complex species was thus ascribed to the extracted tris-complex; the estimated distribution ratio of the metal must have been higher than the true values.

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