Extraction of alkali metal picrates with 18-crown-6, benzo-18-crown-6, and dibenzo-18-crown-6 into various organic solvents. Elucidation of fundamental equilibria governing the extraction-ability and -selectivity.
Author:
Affiliation:
1. Department of Chemistry, Faculty of Science, Chiba University
Publisher
Japan Society for Analytical Chemistry
Subject
Analytical Chemistry
Link
http://www.jstage.jst.go.jp/article/bunsekikagaku/51/7/51_7_515/_pdf
Reference10 articles.
1. 2) Y. Takeda: “Topics in Current Chemistry, Host Guest Complex Chemistry III, The Solvent Extraction of Metal Ions by Crown Compounds”, Vol. 121, Edited by F. Vögtle, E. Weber, p. 1 (1984), (Springer-Verlag, Berlin).
2. 3) 工藤義広, 武田裕行, 松田博明: “機能性大環状化合物の分析化学への応用, 機能性大環状化合物によるイオンの溶媒抽出”, 武田裕行編著, p. 1 (1990), (アイピーシー).
3. Salt complexes of cyclic polyethers. Distribution equilibriums
4. Solvent effects on extraction of potassium picrate with benzo-18-crown-6. A new equation for the determination of ion-pair formation of crown ether-metal salt complexes in water
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