Appealing Copper(I) and Silver(I) Coordination Polymers with an Unprecedented Betainoid Assembling Ligand

Author:

Amelot Dylan1,Hassoun Ammar1,Chamoreau Lise-Marie1,Amouri Hani1,Moussa Jamal1

Affiliation:

1. Sorbonne University, Paris Institute of Molecular Chemistry (UMR 8232), France

Abstract

Two coordination polymers of coinage metals with a rare pyridinium-betainoid L assembling ligand are reported. These polymers are obtained by self-assembly of the linker L and copper(I) or silver(I) ions in acetonitrile. The compounds were characterized by spectroscopic methods and by elemental analysis. The solid-state structures were unambiguously confirmed by single crystal diffraction studies. These assemblies exhibit original helicoidal arrangements. The UV-Vis. absorption and photoluminescence properties are reported as well.

Publisher

Edelweiss Publications Inc

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