Author:
Taís Hartz,Daiane Fischer,de Fraga Karina,Carla Scheeren
Abstract
Palladium nanoparticles (ca. 4.8 nm) were synthesized in presence of 1-n-butyl-3-methylimidazolium tetraflouroborate (BMI.BF4) and 1-n-butyl-3-methylimidazolium hexafluorophosphate (BMI.PF6) and PMI.Si.(OMe)3.Cl functionalized ionic liquids using the sol-gel method. The characteristics of the sol-gel method, ionic liquid on the palladium content was studied, as well as the silica morphology and texture of the support and the hydrogenation activity. The palladium content in the resulting xerogels (ca. 0.22 wt% Pd/SiO2) was shown to be independent of the sol-gel process. The xerogels synthesized in acidic conditions formed materials with larger pore diameters, which in turn might be responsible for the higher catalytic activity in hydrogenation of the alkenes and arenes obtained with the heterogeneous catalyst (Pd/ILs/SiO2).
Publisher
Edelweiss Publications Inc
Subject
General Earth and Planetary Sciences,General Environmental Science