TÜRKİYE EGİRDİR GÖLÜ'NDEKİ ELEMENTLER, PESTİSİTLER VE İYONLAR KİRLETİCİLER:TAYİNİ VE METOT VALİDASYONU
Author:
KILIÇ Murat1ORCID, KILIÇ Serpil1ORCID, PAMUKOĞLU Yunus2ORCID, KIRKAN Bülent2ORCID, ERKAYMAZ Taner2ORCID
Affiliation:
1. ISPARTA UYGULAMALI BİLİMLER ÜNİVERSİTESİ 2. SÜLEYMAN DEMİREL ÜNİVERSİTESİ
Abstract
In this study, the concentrations of elements, ions and pesticides were determined in the samples collected from the Isparta/Egirdir Lake. Firstly, it was validated an analytical method for determination of chlorpyrifos, acetamiprid, methidathion, cyprodinil and pyridaben pesticide residues (total 322 pesticides), ions (total 12 anions/cations) and elements (total 17 elements) in samples. The validation parameters such as linearity, the limit of detection and quantification, selectivity, recovery (%) of the method were determined. The amounts of metal were determined by inductively coupled plasma mass spectrometry (ICP-MS). Arsenic, barium, chromium, copper, iron, manganese, nickel, lead, strontium, vanadium and zinc were determined in different concentrations, but silver, beryllium, cadmium, cobalt, thallium and antimony amounts were not determined. The concentrations of ions were assigned by the ion chromatography (IC). According to the results of these experiments the quantities of lithium, nitrate and phosphate ipns were below the limit of detections in samples. Determination of the pesticides in the same samples was performed on the liquid chromatography-tandem mass spectrometry (LC-MS/MS). The obtained results were discussed.
Publisher
Muhendislik Bilimleri ve Tasarim Dergisi
Subject
Colloid and Surface Chemistry,Physical and Theoretical Chemistry
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