THE INFLUENCE OF 1D AND 2D CARBON NANOMATERIALS ON PROPERTIES OF MAGNESIUM OXYCHLORIDE CEMENT MORTARS

Author:

Zaleska Martina1,Pavlikova Milena2,Pivak Adam2,Pavlik Zbysek2,Jankovsky Ondrej3

Affiliation:

1. Czech Technical University in Prague, Faculty of Civil Engineering / University of Chemistry and Technology, Faculty of Chemical Technology, Department of Inorganic Chemistry

2. Czech Technical University in Prague, Faculty of Civil Engineering

3. University of Chemistry and Technology, Faculty of Chemical Technology, Department of Inorganic Chemistry

Abstract

In this study, magnesium oxychloride cement (MOC) mortars reinforced with multiwalled carbon nanotubes (MWCNT) and graphene were prepared and analyzed. The lower CO2 footprint of MOC in comparison with the production of ordinary Portland cement (OPC) predestines MOC-based materials to be an environmentally sustainable alternative to OPC. However, the wider spread of MOC is hindered by its low water resistance. The combined influence of MWCNT and graphene as 1D and 2D carbon nanomaterials on properties of MOC mortars was experimentally studied in terms of basic physical, microstructural and mechanical parameters assessment. Moreover, the water resistance was investigated in detail based on the measurement of hygric parameters and softening coefficient after 24 h exposure to water. The addition of nanomaterials was (0.25+0.25) wt.% and (0.5+0.5) wt.% of MOC binder. The results showed that the combined addition of 1D and 2D carbon nanomaterials led to a reduction in average pore diameter, and thus quite obvious improvement in water resistance compared to the control MOC mortar. The developed nano-doped MOC mortars appear to be perspective materials that might find application in the construction industry.

Publisher

STEF92 Technology

Reference13 articles.

1. [1] Regulation (EU) 2021/1119 of the European Parliament and of the Council of 30 June 2021 establishing the framework for achieving climate neutrality and amending Regulations (EC) No 401/2009 and (EU) 2018/1999 (�European Climate Law�).

2. [2] International Energy Agency. Available online: https://www.iea.org/fuels-andtechnologies/ cement (accessed on 11 January 2023).

3. [3] Zaleska M., Pavlikova M., Pivak A., Marusiak S., Jankovsky O., Lauermannova A. M., Lojka M., Antoncik F., Pavlik Z., MOC doped with graphene nanoplatelets: the influence of the mixture preparation technology on its properties, Materials, vol. 14, 1450, 2021.

4. [4] Wang Y., Wei L., Yu J., Yu K., Mechanical properties of high ductile magnesium oxychloride cement-based composites after water soaking, Cement and Concrete Composites, vol. 92, pp 248-258, 2019.

5. [5] He P., Poon Ch. S., Tsang D. C. W., Using incinerated sewage sludge ash to improve the water resistance of magnesium oxychloride cement (MOC), Construction and Building Materials, vol. 147, pp 519-524, 2017.

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