NEW DATA ON MINERALS WITH ECONOMIC POTENTIAL PRESENT IN LITHIUM PEGMATITES FROM CON?U � NEGOVANU, CIBIN (CINDREL) MOUNTAINS, CENTRAL GROUP, SOUTHERN CARPATHIANS, ROMANIA

Author:

Calin N.1,Constantina C.1,Perta D.1

Affiliation:

1. Geological Institute of Romania

Abstract

In this paper will discuss the minerals present in pegmatites, seen as a way of storing chemical elements, important from an economic point of view. The study area is called Con?u - Negovanu, and is located between the two mountain massifs known as Cindrel (Cibin) and Lotru Mountains. Muscovite (seen as a possible indicator for lithium in Con?u � Negovanu pegmatites), one of the important minerals alongside quartz, spodumene, and albite cleavelandite variety, is probably the mineral that includes in its structure chemical elements: Fe3+, Fe2+, Mg2+, Mn2+, Ti, Li, Nb, Ta, Sn, Ce, K, Na, Ca2+ which tend to materialize in minerals such as triphylite - lithiophilite, ferrisicklerite, heterosite - purpurite, amblygonite � montebrasite, "ferrogatehouseite", fluorapatite, hydroxylapatite, vivianite, wolfeite, maricite, monazite, cassiterite, titanite, spodumene, cookeite. In addition to these, we indicate beryl, scarce schorl, uraninite, garnets, kyanite, staurolite and columbite - group minerals. Phyllosilicates viewed through the mineralogical prism of pegmatites provide information on crystallization, mainly temperature (the presence of the 2M1 polytype indicates a high temperature) and the evolution pressure of pegmatitic melts. Plagioclase (oligoclase and albite) is partially or replaced by muscovite and quartz - a stable association in the later stages of pegmatites, following the crystallization of microcline by reducing the formation of muscovite, and if there is an increase in water content, the proportion changes, the microcline is partially or replaced of muscovite. Chemical analysis: EPMA indicates in muscovite the presence of FeO with an average value of 1.44 %, and Na2O with an average value of 0.44 %, fluorine occurs in proportions with values from 0.04 to 0.30 %.

Publisher

STEF92 Technology

Reference9 articles.

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2. [2] Calin, N., Constantina, C., Bala?cu?a, E.R.: Spodumene and Beryl from Con?u lithium � pegmatites, Cindrel (Cibin) Mountains, Central Group, South Carpathians, Romania. Carpathian Journal of Earth and Environmental Sciences February 2023, Vol. 18, No. 1, p. 183 � 194; DOI:10.26471/cjees/2023/018/250. 2023 [3a] Cerny, P.: Anatomy and classification of granitic pegmatites. In Granitic Pegmatites in Science and Industry. (P. Cerny, ed.). Mineral. Assoc. Can., Short Course Handbook 8, 1 � 39. 1982 a. [3b] Cerny, P.: Petrogenesis of granitic pegmatites. In Granitic Pegmatites in Science and Industry (P. Cerny, ed.). Mineral. Assoc. Can., Short Course Handbook 8, 405 � 461. 1982 b.

3. [4] Gatta, G.D., Mcintyre, G. J., Sassi, R., Rotiroti, N. and Pavese, A.: Hydrogen � bond and cation partitioning in muscovite: A single � crystal neutron � diffraction study at 295 and 20 K. American Mineralogist, Volume 96, pages 34 � 41. 2011

4. [5] Hann, H. P.: Pegmatites from the Southern Carpathians, Publishing House of the Academy of the Socialist Republic of Romania, Bucharest. p. 141. 1987 (in romanian).

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