SiO2气凝胶薄膜常压制备与强化研究

Author:

Wu Guang-Ming ,Lu Hong-Yan ,Wang Yu ,Shen Jun ,Zhou Bin ,Zhang Qin-Yuan ,Deng Zhong-Sheng ,

Abstract

Scratch resistantsilicaaerogelfilmswitha 77%porosityand 1 . 1 2refractiveindexatambientpressureisreportedusingtheexchangeofsolventandmodificationof—CH3 group.Thesilicafilmswerepreparedinasol gelprocessbyadip coatingmethod ,andthenwerepostannealedinairandamixedgasatmosphere.Thefilmswerecharacterizedwithtransmissionelectronmicroscope,scanningelectronmicroscope,FourierTransforminfraredspectroscope,anellipsometer,andtheabrasiontest,respectively.Withthepostannealing,thefrequencyshiftofFTIRabsorptionω4(TO3 )peakofthefilmstoalowerwavenumberresultsfromadecreaseintheaverageSi—O—Sibridgingangle.Anincreaseinthefullwidthathalf maximum (FWHM)oftheω4peakisascribedtoawidedistributionofthebridginganglebecauseoftheformationofstrainedSi—O—Sibondscausedbythepostannealing.Theabrasionandadhesiontestsindicatethatthemixedgastreatmentnoticeablystrengthensthesilicanetwork .TheincreaseinstrengthisattributedtomoreSi—O—Sibondcross linkagesbetweensilicaparticlesformedbythemixedgastreatment.

Publisher

Acta Physica Sinica, Chinese Physical Society and Institute of Physics, Chinese Academy of Sciences

Subject

General Physics and Astronomy

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