THE ANGULAR MOMENTUM ORIENTATION OF C2H221 AND ITS COLLISIONAL DECAY AND TRANSFER
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Published:1999
Issue:5
Volume:48
Page:862
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ISSN:1000-3290
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Container-title:Acta Physica Sinica
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language:
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Short-container-title:Acta Phys. Sin.
Author:
CAO WEN-BING ,A.D.RUDERT ,J.MARTIN ,H.ZACHARIAS ,J.B.HALPERN ,
Abstract
The rotational angular momentum orientation of acetylene in vibrationally excited discrete rotational state (X1Σ+g,ν″2=1,J″) has been selectively prepared by circularly polarized laser stimulated Raman pumping. From the induced fluorescence by a circularly polarized UV laser, A1Au(ν′3=1)←X1Σ+g(ν″2=1), the orientation of C2H2(X1Σ+g,ν″2=1,J″=4,7,8,…,13)is measured for the first time. The decay rate constants and transfer of the orientation from the initial excited level to neighboring rotational states have been extracted.
Publisher
Acta Physica Sinica, Chinese Physical Society and Institute of Physics, Chinese Academy of Sciences
Subject
General Physics and Astronomy