External characteristics of lithium-ion power battery based on electrochemical aging decay model

Abstract

The current electrochemical models of lithium-ion power batteries have many problems, such as complex models, difficult modeling, low computational efficiency and poor aging evaluation effect. In this paper, a mechanism model (ADME) considering battery decay and aging is proposed. In this paper, the pseudo-two-dimensions (P2D) electrochemical model is first reduced by finite difference method to obtain a simplified P2D (SP2D). On the basis of SP2D model, a mechanism model considering battery decay and aging is proposed, which is based on the degradation and aging phenomenon caused by the side reactions between positive and negative electrodes. Secondly, the multivariate deviation compensation least square method is used to identify the model parameters. Finally, the terminal voltage output of SP2D model is compared with that of ADME model and the outputs from the two models are also analyzed through the cycle experiment on power battery aging performance, constant current and pulse condition. The results show that the ADME model is relatively simple, has high computational efficiency and estimation accuracy, and can effectively evaluate the aging decline of battery capacity, and obtain the ideal external characteristic curve of lithium ion power battery.