Chemical pressure effects in ZrCuSiAs-type manganese-based compound ThMnSbN
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Published:2022
Issue:4
Volume:71
Page:046103
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ISSN:1000-3290
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Container-title:Acta Physica Sinica
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language:
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Short-container-title:Acta Phys. Sin.
Author:
Xiao Yu-Sen,Duan Qing-Chen,Li Bai-Zhuo,Liu Shao-Hua,Zhu Qin-Qing,Tan Shu-Gang,Jing Qiang,Ren Zhi,Mei Yu-Xue,Wang Cao,Cao Guang-Han, , ,
Abstract
A quasi-two-dimensional manganese-based compound ThMnSbN is synthesized by the solid-state reaction method. Structural refinement based on X-ray powder diffraction shows that the compound structure belongs to the <i>P</i>4/<i>nmm</i> space group. The lattice parameters are <i>a</i> = 4.1731 Å and <i>c</i> = 9.5160 Å. Electrical transport measurements show that the resistivity of the compound is the lowest in the Mn-based family. When cooling it, its resistivity rises slowly and shows a shoulder-like anomaly at 16 K. Also, the magnetic susceptibility exhibits an anomaly at the very same temperature. Though the specific heat data indicate the inexistence of transition-induced anomaly, the electron specific heat coefficient of <i>γ</i> = 19.7 mJ·mol<sup>–1</sup>·K<sup>–2</sup> is derived by fitting the low-temperature <i>C</i>-<i>T</i> curve. This <i>γ</i> value is much higher than those of the isostructural manganese-based compounds. Thus, the specific heat is consistent with the low resistivity, implying a considerable electronic density of states near the Fermi surface for ThMnSbN. By comparing the crystal structure for a group of ZrCuSiAs-type compounds, various chemical pressure effects of the fluorite-type Th<sub>2</sub>N<sub>2</sub> layer on the conducting layer in different compounds are discussed.
Publisher
Acta Physica Sinica, Chinese Physical Society and Institute of Physics, Chinese Academy of Sciences
Subject
General Physics and Astronomy
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