Stability of simulated wasted forms (Sr1-1.5xYx) TiO3 immobilizing 90Y
-
Published:2014
Issue:18
Volume:63
Page:182802
-
ISSN:1000-3290
-
Container-title:Acta Physica Sinica
-
language:
-
Short-container-title:Acta Phys. Sin.
Author:
Mu Wan-Jun ,Xie Xiang ,Li Xing-Liang ,Yu Qian-Hong ,Zhang Rui ,Lü Kai ,Tang Hui ,Zhou Guan-Hong ,Wei Hong-Yuan ,
Abstract
In order to study the stability of perovskite-type SrTiO3 used for immobilizing Y3+, Sr (NO3)2, TiO2 and Y2O3 are used as starting materials. The synthesized Y2O3-doped SrTiO3 can be generally represented as Sr1-1.5xYxTiO3 (0≤ x≤0.12) with the high temperature solid reaction. The phases, structures and microcosmic shapes of synthetic condensates are characterized by the X-ray diffraction, Raman and scanning electron microscopy, and long-term chemical stability is studied at 90 ℃. The results indicate that the phases of compounds change from perovskite to pyrocholre phase when the value of x is more than 0.08. The leaching rates of Sr2+ and Y3+ in waste form increase with the increase of immersion time. The highest leaching concentrations of Sr2+ and Y3+ for 42-day immersion are no more than 0.004 and 0.02 μg·mL-1, respectively.
Publisher
Acta Physica Sinica, Chinese Physical Society and Institute of Physics, Chinese Academy of Sciences
Subject
General Physics and Astronomy
Reference26 articles.
1. Ojovan M I, Lee W E 2005 Netherlands (Amsterdam: Elsevier Science Publishers) pp213-215
2. Yang J W, Luo S G, Li B J 2001 At. Enegy. Sci. Technol. 35 (suppl) 104 (in Chinese)[杨建文, 罗上庚, 李宝军 2001 原子能科学与技术(增刊) 35 104]
3. Ewing R C 1999 National Academy of Science Colloquium 3 3432
4. Jaffe J E, Renee M, Jiang W L 2012 Computat. Mater. Sci. 53 153
5. Rao K R 2001 Current Sci. 12 1543