Crystal field energy-levels of Nd3+:Gd3Sc2Al3O12 and fitting

Author:

Guo Chang-Xin ,Tan Xiao-Liang ,Liu Wen-Peng ,Yin Shao-Tang ,Jiang Hai-He ,Xiao Jin ,Xia Shang-Da ,Zhang Qing-Li ,Zhou Wen-Long , , ,

Abstract

Nd3+ :GSAG, a laser crystal of 942 nm with good performance, was grown by Czochralski method successfully, and its transmission spectra at room temperature were studied. Sixty-eight crystal field splitting levels of Nd3+ with the maximum up to 29967 cm-1 were identified, to which the Hamiltonian parameters of free-ion and crystal field were fitted, and the root-mean-square deviation of energy level fitting is 16.7 cm-1, which indicated that the experimental and calculated energy levels are well consistent. The obtained Hamiltonian parameters can be used to calculate the wavefunctions of Nd3+ in GSAG, predict its energy level splitting, study the luminescent properties and so on.

Publisher

Acta Physica Sinica, Chinese Physical Society and Institute of Physics, Chinese Academy of Sciences

Subject

General Physics and Astronomy

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