Author:
Xu Yan ,Zhao Juan ,Wang Jun ,Liu Fang ,Meng Qing-Tian ,
Abstract
Quasi-classical trajectory calculations are carried out for the exothermic reaction H+BrF→HBr+F on the latest London-Eyring-Polanyi-Sato potential energy surface. The product angular distributions which reflect the vector correlation are calculated. Polarization dependent differential cross sections which are sensitive to many photoinitiated bimolecular reactions are presented in the center of mass frame. The calculated results suggest that the product rotational polarization becomes stronger as collision energy increases and the products were mainly backward scatteried. By comparing the product polarization of reactions D+BrF→DBr+F and H+BrF→HBr+F, the isotope effects have also been revealed.
Publisher
Acta Physica Sinica, Chinese Physical Society and Institute of Physics, Chinese Academy of Sciences
Subject
General Physics and Astronomy
Cited by
5 articles.
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