Affiliation:
1. Institute of Environmental and Municipal Engineering, North China University of Water Conservancy and Electric Power, Zhengzhou 450011, P. R. China
Abstract
A metal-organic framework [Cd(dppip)]n (1) based on 5-(diphenylphosphino)isophthalic acid (H2dppip) has been synthesized hydrothermally and characterized by IR spectroscopy, elemental analysis, and X-ray crystallography. [Cd(dppip)]n shows a sheet structure owing to carboxylate bridging with windows with dimensions 10.692 x 9.325 Å2. The layers are further connected through P-Cd interactions to give a three-dimensional supramolecular network. The thermal analysis (DTA) of complex 1 exhibited an exceptionally high thermal stability (m. p. 452:8 °C). The compound shows fluorescence at ca. 418 nm upon excitation at 314 nm
Cited by
2 articles.
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