An Intramolecular Boron Nitrogen Lewis Acid Base Pair on a Rigid Naphthyl Backbone-Reference-Cited by-同舟云学术

An Intramolecular Boron Nitrogen Lewis Acid Base Pair on a Rigid Naphthyl Backbone

Published:2012-06-01 Issue:6 Volume:67 Page:589-593
ISSN:1865-7117
Container-title:Zeitschrift für Naturforschung B
language:en
Short-container-title:

Author:

Winkelhaus Daniel¹,Neumann Beate¹,Mitzel Norbert W.¹

Affiliation:

1. Lehrstuhl für Anorganische Chemie und Strukturchemie, Universität Bielefeld, Universitätsstraße 25, 33615 Bielefeld, Germany

Abstract

The reaction of (C6F5)2BCl with 8-lithio-N,N-dimethyl-1-naphthylamine (1) afforded the fivemembered ring system 8-bis(pentafluorophenyl)boryl-N,N-dimethyl-1-naphthylamine (2) with an intramolecular dative B-N bond. The compound was characterised by elemental analysis, NMR spectroscopy and single-crystal X-ray diffraction.

Publisher

Walter de Gruyter GmbH

Subject

General Chemistry

Link

https://www.degruyter.com/document/doi/10.5560/znb.2012-0091/pdf

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