3,3’’-Bis(saccharin-6-ylmethyl)-1,1’:3’,1’’-terphenyl – Precursor of A New Tetradendate Bis-bridging Ligand

Author:

Buck Stefan1,Maas Gerhard1

Affiliation:

1. Institut für Organische Chemie I, Universität Ulm, Albert-Einstein-Allee 11, 89081 Ulm, Germany

Abstract

The title compound (H2tpsac) was synthesized from 6-bromosaccharin and 3,3’’-bis(bromomethyl)- m-terphenyl. The ability of tpsac to serve as a tetradentate bis-bridging ligand was demonstrated by the formation of the dinuclear ruthenium(I,I) complexes [Ru2(CO)5(μ,μ-tpsac)]2, [Ru2(CO)4(μ,μ-tpsac)]n, [Ru2(CO)4(PPh3)2(μ,μ-tpsac)], and [Ru2(CO)5(PPh3)(μ,μ-tpsac)]. An X-ray crystal structure analysis of [Ru2(CO)4(PPh3)2(μ,μ-tpsac)] showed the head-to-tail (or 1,1) arrangement of the two saccharinate coordination sites.

Publisher

Walter de Gruyter GmbH

Subject

General Chemistry

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