Novel Dihydropyrazines and their Double ortho-Annulation to Hexaazapentacenes-Reference-Cited by-同舟云学术

Novel Dihydropyrazines and their Double ortho-Annulation to Hexaazapentacenes

Published:2014-05-01 Issue:5 Volume:69 Page:641-649
ISSN:1865-7117
Container-title:Zeitschrift für Naturforschung B
language:en
Short-container-title:

Author:

Strathausen Rainer¹²,Beckert Rainer¹,Fleischhauer Jan¹,Müller Dirk³,Görls Helmar⁴

Affiliation:

1. Institut für Organische Chemie und Makromolekulare Chemie, Friedrich-Schiller-Universität Jena, Humboldtstr. 10, D-07743 Jena, Germany

2. Present address: Biomolecular Photonics Group, Jena University Hospital, Nonnenplan 4, D-07743 Jena, Germany

3. Klinikum Bad Berka, Department of Molecular Radiotherapy / Center for Molecular Imaging, D-99437 Bad Berka, Germany

4. Institut für Anorganische und Analytische Chemie, Friedrich-Schiller-Universität Jena, Lessingstr. 8, D-07743 Jena, Germany

Abstract

The cycloacylation of oxalic amidines 7 with bis-imidoylchlorides 6 furnished the dihydropyrazine derivatives 8. Due to their vicinal amino-imino substructures, they provide good preconditions for a double intramolecular ring closure reaction. An alternative synthesis for hexaaza-pentacenes 1 was developed using potassium carbonate as the base and lead tetraacetate as the oxidizing agent.

Publisher

Walter de Gruyter GmbH

Subject

General Chemistry

Link

https://www.degruyter.com/document/doi/10.5560/znb.2014-4002/pdf

Cited by 9 articles. 订阅此论文施引文献订阅此论文施引文献，注册后可以免费订阅5篇论文的施引文献，订阅后可以查看论文全部施引文献

1. Syntheses of linear azapentacenes;Progress in Heterocyclic Chemistry;2023

2. Ethylene‐Bridged Tetradentate Bis(amidines): Supramolecular Assemblies through Hydrogen Bonding and Photoluminescence upon Deprotonation;European Journal of Organic Chemistry;2020-05-27

3. Ethylene-Bridged Hexadentate Bis(amidines) and Bis(amidinates) with Variable Binding Sites;The Journal of Organic Chemistry;2019-09-27

4. Fluorescent heterocycles: Recent trends and new developments;Advances in Heterocyclic Chemistry;2019

5. 5,12‐Diacetyl‐5,12‐dihydroquinoxalino[2,3‐ b ]quinoxalines: Solid‐State Fluorescence, AIE Properties, and Orbital Switching by Substituent Effect;Chemistry – An Asian Journal;2018-06-19