Convenient Synthesis and Molecular Structure of PPN[RhCl2(CO)2] (PPN+ = Bis(triphenylphosphane)iminium)

Author:

Böttcher Hans-Christian1,Mayer Peter1

Affiliation:

1. Department Chemie, Ludwig-Maximilians-Universität, Butenandtstraße 5 – 13, D-81377 München, Germany

Abstract

The reaction of hydrated rhodium(III) chloride with formic acid in refluxing ethoxyethanol afforded in a convenient way the known rhodium carbonyl chlorido complex anion cis-[RhCl2(CO)2]-. This species was formed in good yield and was characterized as its PPN salt (PPN+ = bis(triphenylphosphane)iminium cation). The molecular structure of the title compound PPN[RhCl2(CO)2] was confirmed by X-ray diffraction and shown to be isomorphous to PPN[IrCl2(CO)2]

Publisher

Walter de Gruyter GmbH

Subject

General Chemistry

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