Organometallic Lewis Acids, Part LVIIII [1]. Directed Synthesis of Dinuclear Metal Carbonyl Complexes of Rhenium, Iron, Chromium, and Tungsten with a Single Unsupported Halide or Pseudohalide Bridge (Cl-, Br-, I-, CN-, C(CN)3 -, NCS-, PPh2 -, SH-) by Use of Re(CO)5FBF3-Reference-Cited by-同舟云学术

Organometallic Lewis Acids, Part LVIIII [1]. Directed Synthesis of Dinuclear Metal Carbonyl Complexes of Rhenium, Iron, Chromium, and Tungsten with a Single Unsupported Halide or Pseudohalide Bridge (Cl-, Br-, I-, CN-, C(CN)3 -, NCS-, PPh2 -, SH-) by Use of Re(CO)5FBF3

Published:2014-12-01 Issue:11-12 Volume:69 Page:1215-1220
ISSN:1865-7117
Container-title:Zeitschrift für Naturforschung B
language:en
Short-container-title:

Author:

Fritz Peter M.¹,Sacher Wolfgang¹,Beck Wolfgang¹

Affiliation:

1. Department Chemie der Ludwig-Maximilians-Universität München, Butenandtstr. 5 – 13, 81377 München, Germany

Abstract

Abstract By use of Re(CO)5FBF3 the complexes with a single unsupported halide or pseudohalide bridge [Cp(OC)2Fe-X-Re(CO)5]+ BF4 - (X=Cl, I, PPh2), (OC)5M-X-Re(CO)5 (M=Cr, W; X=Br, I, CN, NCS, SH), (OC)5W-N≡C-C[-C≡N-Re(CO)5]2 + BF4 -, Cp(OC)(NC)Fe-C≡N-Re(CO)5, and [(OC)5Re-N3-Re(CO)5]+ BF4 - have been synthesized.

Publisher

Walter de Gruyter GmbH

Subject

General Chemistry

Link

https://www.degruyter.com/document/doi/10.5560/znb.2014-4095/pdf

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