CsOH and its Lighter Homologues – a Comparison

Author:

Wörsching Matthias1,Hoch Constantin1

Affiliation:

1. Department Chemie, Ludwig-Maximilians-Universität München, Butenandtstraße 5 – 13 (D), D-81377 München, Germany

Abstract

Abstract Cesium hydroxide, CsOH, was for the first time characterised on the basis of single-crystal data. The structure is isotypic to the one of the room-temperature modification of NaOH and can be derived from the NaCl structure type thus allowing the comparison of all alkali metal hydroxide structures. Raman spectroscopic investigations show the hydroxide anion to behave almost as a free ion as in the gas phase. The X-ray investigations indicate possible H atom positions.

Publisher

Walter de Gruyter GmbH

Subject

General Chemistry

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