3-Pyrenylacrylates: Synthetic, Photophysical, Theoretical and Electrochemical Investigations-Reference-Cited by-同舟云学术

3-Pyrenylacrylates: Synthetic, Photophysical, Theoretical and Electrochemical Investigations

Published:2013-04-01 Issue:4 Volume:68 Page:367-377
ISSN:1865-7117
Container-title:Zeitschrift für Naturforschung B
language:en
Short-container-title:

Author:

Reimann Sebastian¹²,Sharif Muhammad¹³⁴⁵,Wittler Kai⁶,Knöpke Leif R.¹,Surkus Annette-E.¹,Roth Christian⁶,Ludwig Ralf¹⁶,Langer Peter¹²

Affiliation:

1. Leibniz-Institut fur Katalyse e.V. an der Universitat Rostock, Albert-Einstein-Str. 29a, 18059 Rostock, Germany

2. Institut fur Chemie, Abteilung Organische Chemie, Universitat Rostock, Albert-Einstein-Str. 3a, 18059 Rostock, Germany

3. Institut fur Chemie, Abteilung Organische Chemie, Universitat Rostock, Albert-Einstein-Str.3a, 18059 Rostock, Germany

4. Department of Chemistry, COMSATS Institute of Information Technology, Abbottabad,Pakistan

5. Equal contribution of these co-authors

6. Institut fur Chemie, Abteilung Physikalische Chemie, Universitat Rostock, Dr. Lorenz Weg 1, 18059 Rostock, Germany

Abstract

The Mizoroki-Heck coupling of 1-bromopyrene with acrylates provides a convenient access to a variety of 3-pyrenylacrylates in very good yields (up to 93%). Their photophysical properties combined with solvatochromic effects were studied. In addition, electrochemical oxidation potentials were determined by DPV (differential pulse voltammetry) measurements. The fine structure of the absorbance spectra obtained from photophysical measurements are compared with the results of theoretical calculations performed by time dependent TD-B3LYP methods using the 6-31G* basis set.

Publisher

Walter de Gruyter GmbH

Subject

General Chemistry

Link

https://www.degruyter.com/document/doi/10.5560/znb.2013-3004/pdf

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