Synthesis, Structure and Properties of a 2D Cadmium(II) Coordination Polymer Based on Fluconazole and Isophthalate Ligands

Author:

Pan Gang-Hong1,Tang Jing-Niu1,Yin Xian-Hong1,Tian Wei-Man1,Huang Zhong-Jing1

Affiliation:

1. College of Chemistry and Ecological Engineering, Guangxi University for Nationalities, Nanning 530006, P. R. China

Abstract

A Cd(II) complex based on fluconazole and isophthalate ligands, {[Cd(HFlu)(IPA)(H2O)] · H2O}n (1), (HFlu=fluconazole; H2IPA=isophthalic acid) has been synthesized. Single-crystal X-ray analysis reveals that complex 1 has a 2D network structure including unusual triple hydrogen bonds between hydroxyl and triazolyl groups. The complex has also been characterized by IR, UV=Vis and fluorescence spectroscopy, elemental analysis, and thermogravimetry

Publisher

Walter de Gruyter GmbH

Subject

General Chemistry

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