A Dinuclear Palladium(II) Complex of the {N(SPPh2)2}- Ligand – Synthesis and Structure

Abstract

The synthesis and characterization including the crystal structure of the dinuclear palladium( II) complex [(k-S,S’)-{N(SPPh2)2}Pd(m-{k2-S'',S'''})-{N(SPPh2)2}PdCl2] (1) are reported. Compound 1 was obtained from the reaction of [PdCl2(COD)] (COD=1,5-cyclooctadiene) and HN(SPPh2)2 in a 1:1 molar ratio in CH2Cl2. The {N(SPPh2)2}- ligands act both as bridging and/or terminally chelating units