Affiliation:
1. Key Laboratory of Polyoxometalate Chemistry of Henan Province, Institute of Molecular and Crystal Engineering, College of Chemistry and Chemical Engineering, Henan University, Kaifeng 475004, P. R. China
Abstract
A new Ag(I) coordination polymer [AgL(NO3)]n 1 (L=4-(pyridine-2-yl)methyleneamino-1,2,4- trizaole) has been synthesized and characterized by IR spectroscopy, elemental analysis, powder and single-crystal X-ray diffraction. The Ag(I) atom has a seesaw environment with an N3O donor set from three N atoms of two ligands and one O atom of one NO-
3 anion. Each twisted tridentate ligand is bound to two silver centers, and each silver atom is coordinated by two ligands thereby generating a zigzag chain structure. The chains interact with each other featuring a three-dimensional supramolecular network through multiple weak C-H···π interactions and C-H···O hydrogen bonds. The luminescence properties of the polymer 1 were investigated in the solid state at room temperature.
Cited by
7 articles.
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1. Synthesis, Characterization and Crystal Structure of Samarium(III)-(E)-1-phenyl-N-(4H-1,2,4-triazol-4-yl)methanimine Complex;Jordan Journal of Chemistry;2021-08-01
2. Synthesis, antimicrobial and antimutagenic effects of novel polymeric-Schiff bases including indol;Journal of Molecular Structure;2019-11
3. Modulation of Electronic Mobility of a One‐Dimensional Coordination Polymeric Molecular Wire with Light;Chemistry – An Asian Journal;2019-08-23
4. Unusual Polynuclear Copper(II) Complexes with a Schiff-Base Ligand Containing Pyridyl and 1,2,4-Triazolyl Rings;Journal of Cluster Science;2019-05-07
5. Lanthanide(III) (Eu, Gd, Tb, Dy) Complexes Derived from 4-(Pyridin-2-yl)methyleneamino-1,2,4-triazole: Crystal Structure, Magnetic Properties, and Photoluminescence;Chemistry - An Asian Journal;2018-07-19