Novel Tin(IV) Complexes with the Hybrid Guanidine Ligand DMEGqu-Reference-Cited by-同舟云学术

Novel Tin(IV) Complexes with the Hybrid Guanidine Ligand DMEGqu

Published:2013-06-01 Issue:5-6 Volume:68 Page:653-665
ISSN:1865-7117
Container-title:Zeitschrift für Naturforschung B
language:en
Short-container-title:

Author:

Jesser Anton¹,Vieira Ines dos Santos²,Herres-Pawlis Sonja¹

Affiliation:

1. Department Chemie, Ludwig-Maximilians-Universität M¨unchen, Butenandtstraße 5 – 13, 81377 München, Germany

2. Anorganische Chemie II, Technische Universität Dortmund, Otto-Hahn-Straße 6, 44227 Dortmund, Germany

Abstract

Novel Sn(IV) complexes with the guanidine-quinoline hybrid ligand DMEGqu are reported. With SnCl4, SnBr4, Me2SnCl2, Me2SnBr2, and the 3,5-di-tert-butyl-catecholate coligand complexes with different donor sets were synthesized. Four of these tin compounds have been modelled by density functional theory. Additionally, a tetranuclear Sn(IV) oxocluster with a novel structure motif, a distorted hetero-adamantane with bridging oxido and hydroxido ligands, is presented

Publisher

Walter de Gruyter GmbH

Subject

General Chemistry

Link

https://www.degruyter.com/document/doi/10.5560/znb.2013-3080/pdf

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