Standard Electrode Potential of Hg | Hg2Cl2(s), Cl- Electrode in Dioxane-Water Media at a Number of Temperature and the Related Thermodynamic Quantities

Author:

Shamsuddin Md.1,Chaohadia Anil Kumar2

Affiliation:

1. Maharana Pratap Govt. P.G. College, Chittorgarh, Rajasthan, India

2. Department of Chemistry, Patna University, Science College, Patna, Bihar, India

Abstract

From e.m.f measurements of cells (C-1) and (C-2) it has been established that modified Davies equation is valid in dioxane-water media at least upto 30% dioxane by weight. E0m values of Hg | Hg2Cl2(s), Cl- electrode in dioxane-water media having 10, 20 and 30% dioxane by weight and the corresponding thermodynamic parameters have been determined at 288.15, 298.15, 308.15 and 318.15 0K. (Pt),H2 ( l atm ) | HCl(m1) x% Dioxane (100-x)% H2O, Hg2Cl2(s) | Hg … (C-1) (Pt),H2 ( l atm ) | HCl(m1) BaCl2(m2)x% Dioxane (100-x)% H2O, Hg2Cl2(s) | Hg … (C-2)

Publisher

Technoscience Academy

Subject

Industrial and Manufacturing Engineering,Polymers and Plastics,Business and International Management

Reference14 articles.

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2. G. Sahu and B. Prasad, J. Indian Chem. Soc., 1969, 45, 233.

3. A. K. Sinha, J. C. Ghosh and B. Prasad, J. Indian Chem. Soc., 1974, 51, 586.

4. B. Prasad, J. Indian Chem. Soc., 1977, 54, 488.

5. A. Gupta, Ph.D. Thesis, Patna University, 1986.

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