ANALYSIS AND EVALUATION OF THE BIOGAS PURIFICATION TECHNOLOGIES FROM H2S

Abstract

H2S concentrations in biogas are limited by environmental regulations. Because these gases are toxic to human health, cause corrosion, and damage the combined heat and power (CHP) engines and other metallic parts after burning. Hence, the following requirements must be met by a biogas purification method: 1 – high H2S removal efficiency (RE), 2 – stability over a long period of time, 3 – low cost, 4 – minimal biogas dilution, and 5 – straightforward structure. There are various physical, chemical, and biological technologies, which can be undertaken to meet earlier mentioned criteria and efficiently remove H2S from biogas. In this study, electrochemical oxidation, adsorption by zeolite, pressure swing adsorption, adsorption on activated carbon, adsorption on metal oxides, adsorption on nano-particles, metal sulfide precipitation, water scrubbing, membrane separation, organic solvents (amine), microaeration, and purification by sulfur-oxidizing bacteria (anoxic, aerobic, anaerobic), will be introduced, while their pros and cons are compared and discussed in detail.