Removal of methylene blue (MB) by bimetallic- metal organic framework

Author:

Al Amery Naser,Abid Hussein Rasool,Wang ShaobinORCID,Liu ShaominORCID

Abstract

In this study, three improved versions of UiO-66 metal organic frameworks (MOFs) were synthesised successfully: Different ratios of Ca+2/Zr+4 were used to synthesise UiO-66, UiO-66-10%Ca and UiO-66-30%Ca. Batch adsorption experiments were achieved to remove MB from wastewater by UiO-66-Ca. UiO-66-10%Ca exhibited the highest adsorption capacity with maximum  MB adsorption capacity of 15 mg. g–1 in UiO-66-30%Ca while UiO-66 demonstrated lower MB loading. Langmuir and Freundlich models have been employed to describe isotherms. A kinetics study indicated pseudo first-order and pseudo second-order equations. In addition, an intraparticle diffusion model was utilised. The results presented here may facilitate the further enhancement of UiO-66 MOFs and advance the synthesis of multimetal MOFs in future research.

Publisher

Lembaga Penelitian dan Pengabdian kepada Masyarakat Universitas Riau

Subject

General Medicine,General Chemistry

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