Gadolinyum(III) Asetat İçeren Yeni Tetrapirazinoporfirazinin Sentezi ve Spektroskopik Özellikleri
Author:
PİŞKİN Mehmet1ORCID, ODABAŞ Zafer2ORCID, DURMUŞ Mahmut3ORCID
Affiliation:
1. Çanakkale Onsekiz Mart University, Çanakkale Vocational School of Technical Sciences, Department of Food Processing 2. Marmara University, Faculty of Arts and Sciences, Department of Chemistry 3. Gebze Technical University, Faculty Of Basic Sciences, Department of Chemistry
Abstract
A new tetrakis-(2-methylpyrazino)porphyrazinato gadolinium(III) acetate complex was synthesized. Elemental analysis, Fourier-Transform Infrared, Ultraviolet-visible, and fluorescence spectroscopy techniques clarified its structure. It can dissolve very well without aggregation in both Dimethyl sulfoxide and N, N-Dimethylformamide, which have high dielectric constant and high dipole moment from polar aprotic solvent type. Its aggregation property was also investigated in dimethyl sulfoxide at different concentrations, and it was determined to contain monomeric species. In addition, its fluorescence properties were investigated in Dimethyl sulfoxide and the effect of gadolinium(III) acetate metal ion as a heavy rare earth element was determined. According to the findings in this study, it may be used as an electronic and optical material and in various technological applications such as photocatalytic applications. In addition, these findings may be useful for systems that include changes in pyrazinoporphyrazine-like forms.
Funder
Çanakkale Onsekiz Mart University the Scientific Research Coordination Unit
Publisher
Afyon Kocatepe Universitesi Fen Ve Muhendislik Bilimleri Dergisi
Subject
General Engineering
Reference13 articles.
1. Donzello, M.P., Ercolani, C., Novakova, V., Zimcik, P., and Stuzhin, P.A., 2016. Tetrapyrazinoporphyrazines and their metal derivatives. Part I: Synthesis and basic structural information. Coordination Chemistry Reviews, 309, 107–179. 2. Donzello, M.P., Viola, E., Bergami, C., Dini, D., Ercolani, C., Giustini, M., Kadish, K.M., Meneghetti, M., Monacelli, F., Rosa, A., 2008. Tetra-2,3-pyrazinoporphyrazines with Externally Appended Pyridine Rings. Chemical and Redox Properties and Highly Effective Photosensitizing Activity for Singlet Oxygen Production of Penta- and Monopalladated Complexes in Dimethylformamide Solution. Inorganic Chemistry, 47, 8757–8766. 3. Donzello, M.P., Viola, E., Cai, X., Mannina, L., Ercolani, C., Kadish, K.M., 2010. Tetra-2,3-pyrazinoporphyrazines with Externally Appended Pyridine Rings. Central (ZnII, CuII, MgII(H2O), CdII) and Exocyclic (PdII) Metal Ion Binding in Heteropentametallic Complexes from Tetrakis-2,3-[5,6-di(2-pyridyl)pyrazino]porphyrazine. Inorganic Chemistry, 49, 2447–2456. 4. Kudrevich, S.V., van Lier, J.E., 1996. Azaanalogs of phthalocyanine: syntheses and properties. Coordination Chemistry Reviews, 156, 163-182 5. Kopecky, K., Šatínský, D., Novakova, V., Miletin, M., Svoboda, A., Zimcik, P., 2011. Synthesis of mono-, di-, tri- and tetracarboxy azaphthalocyanines as potential dark quenchers. Dyes and Pigments, 91, 112–119.
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