n -Alkanes to n -alcohols: Formal primary C─H bond hydroxymethylation via quadruple relay catalysis-Reference-Cited by-同舟云学术

n -Alkanes to n -alcohols: Formal primary C─H bond hydroxymethylation via quadruple relay catalysis

Published:2020-11-20 Issue:47 Volume:6 Page:
ISSN:2375-2548
Container-title:Science Advances
language:en
Short-container-title:Sci. Adv.

Author:

Tang Xinxin¹^ORCID,Gan Lan¹^ORCID,Zhang Xin¹^ORCID,Huang Zheng¹²³^ORCID

Affiliation:

1. State Key Laboratory of Organometallic Chemistry, Center for Excellence in Molecular Synthesis, Shanghai Institute of Organic Chemistry, Chinese Academy of Sciences, University of Chinese Academy of Sciences, 345 Lingling Road, Shanghai 200032, China.

2. Shenzhen Grubbs Institute, Southern University of Science and Technology, Shenzhen 518055, China.

3. School of Chemistry and Material Sciences, Hangzhou Institute of Advanced Study, University of Chinese Academy of Sciences, 1 Sub-lane Xiangshan, Hangzhou 310024, China.

Abstract

A previously unknown hydroxymethylation reaction directly converts abundant n -alkanes to higher value n -alcohols.

Funder

National Natural Science Foundation of China

Ministry of Science and Technology of the People’s Republic of China

Publisher

American Association for the Advancement of Science (AAAS)

Subject

Multidisciplinary

Reference54 articles.

1. J. Falbe H. Bahrmann W. Lipps D. Mayer G. D. Frey Alcohols Aliphatic in Ullmann’s Encyclopedia of Industrial Chemistry (Wiley-VCH 2013).

2. Production of alcohols via hydroformylation