Charge transport physics of a unique class of rigid-rod conjugated polymers with fused-ring conjugated units linked by double carbon-carbon bonds

Author:

Xiao Mingfei1ORCID,Carey Remington L.1ORCID,Chen Hu2,Jiao Xuechen34,Lemaur Vincent5ORCID,Schott Sam1ORCID,Nikolka Mark1,Jellett Cameron6ORCID,Sadhanala Aditya17ORCID,Rogers Sarah8ORCID,Senanayak Satyaprasad P.19ORCID,Onwubiko Ada6ORCID,Han Sanyang1,Zhang Zhilong1ORCID,Abdi-Jalebi Mojtaba110ORCID,Zhang Youcheng1ORCID,Thomas Tudor H.1,Mahmoudi Najet8ORCID,Lai Lianglun111,Selezneva Ekaterina1ORCID,Ren Xinglong1,Nguyen Malgorzata1,Wang Qijing1,Jacobs Ian1ORCID,Yue Wan12,McNeill Christopher R.3ORCID,Liu Guoming11314ORCID,Beljonne David5,McCulloch Iain26ORCID,Sirringhaus Henning1ORCID

Affiliation:

1. Optoelectronics Group, Cavendish Laboratory, JJ Thomson Avenue, Cambridge CB3 0HE, UK.

2. KSC, King Abdullah University of Science and Technology (KAUST), Thuwal 23955-6900, Saudi Arabia.

3. Department of Materials Science and Engineering, Monash University, Clayton, Victoria 3800, Australia.

4. Australian Synchrotron, 800 Blackburn Road, Clayton, VIC 3168, Australia.

5. Laboratory for Chemistry of Novel Materials, University of Mons, BE-7000 Mons, Belgium.

6. Department of Chemistry, Imperial College London, South Kensington SW7 2AZ, UK.

7. Centre for Nano Science and Engineering, Indian Institute of Science, Bangalore 560012, India.

8. ISIS Pulsed Neutron Source, Rutherford Appleton Laboratory, Didcot OX11 0QX, UK.

9. School of Physical Sciences, National Institute of Science Education and Research, HBNI, Jatni 752050, India.

10. Institute for Materials Discovery, University College London, Torrington Place, London WC1E 7JE, UK.

11. Cambridge Graphene Centre, University of Cambridge, Cambridge CB3 0FA, UK.

12. Key Laboratory for Polymeric Composite and Functional Materials of Ministry of Education, School of Materials Science and Engineering, Sun Yat-Sen University, Guangzhou 510275, China.

13. Beijing National Laboratory for Molecular Sciences, CAS Key Laboratory of Engineering Plastics, CAS Research/Education Center for Excellence in Molecular Sciences, Institute of Chemistry, Chinese Academy of Sciences, Beijing 100190, China.

14. University of Chinese Academy of Sciences, Beijing 100049, China.

Abstract

The charge transport–limiting factors in conjugated polymers without single-bond linkages in the backbone have been identified.

Funder

H2020 European Research Council

Engineering and Physical Sciences Research Council

Publisher

American Association for the Advancement of Science (AAAS)

Subject

Multidisciplinary

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