The existence and impact of persistent ferroelectric domains in MAPbI 3

Author:

Garten Lauren M.1ORCID,Moore David T.1ORCID,Nanayakkara Sanjini U.1ORCID,Dwaraknath Shyam2ORCID,Schulz Philip13,Wands Jake4ORCID,Rockett Angus4,Newell Brian5ORCID,Persson Kristin A.26ORCID,Trolier-McKinstry Susan7ORCID,Ginley David S.1ORCID

Affiliation:

1. National Renewable Energy Laboratory, Golden, CO 80401, USA.

2. Lawrence Berkeley National Laboratory, 1 Cyclotron Rd, Berkeley, CA 94720, USA.

3. CNRS, Institut Photovoltaïque d’Île de France, UMR 9006, 30 route départementale 128, Palaiseau 91120, France.

4. Colorado School of Mines, Golden, CO 80401, USA.

5. Colorado State University, Fort Collins, CO 80523, USA.

6. The Pennsylvania State University, University Park, PA 16802, USA.

7. University of California, Berkeley, Berkeley, CA 94704, USA.

Abstract

We demonstrate a ferroelectric response in MAPbI 3 single crystals that can modulate the electronic response and increase stability.

Funder

Center for the Next Generation of Materials by Design EFRC, U.S. Department of Energy, Office of Science

NREL Director’s Fellowship LDRD

National Center for Photovoltaics funded by the U.S. Department of Energy, Office of Energy Efficiency and Renewable Energy, Office of Solar Energy Technology

Publisher

American Association for the Advancement of Science (AAAS)

Subject

Multidisciplinary

Reference45 articles.

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2. Power conversion efficiency exceeding the Shockley–Queisser limit in a ferroelectric insulator

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4. M. E. Lines A. M. Glass Principles and Applications of Ferroelectrics and Related Materials (Oxford Univ. Press Oxford UK ed. 1 1977).

5. Differentiating ferroelectric and nonferroelectric electromechanical effects with scanning probe microscopy;Balke N.;ACS Nano,2015

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